Graphite Properties, Applications and Optical features.

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Like diamonds in appearance, graphite is made of natural carbon crystals. Atoms are arranged hexagonally and have an opaque dark red to black color. It is found as hexagonal crystals. It can appear earthy, granular or compact. Graphite can be formed through the metamorphism or carbonaceous deposit and hydrothermal reaction. Graphite is the stablest form of carbon in standard conditions. Diamonds can be formed under high temperatures and pressure. It has a very different appearance than a real diamond, and is on the other side of the hardness spectrum. The six carbon atoms arranged horizontally on a plate give it flexibility. The atoms in the ring are very strongly bound, but the bonds between the thin plate are weak. It is used to make pencils and for lubricants. Due to its high conductivity, it is useful in electronic products like batteries, solar cells, and electrodes.

Chemical Properties

Chemical Classification Native element
Formula C

Graphite Physical Properties

Color Steel gray and black
Streak Black
Luster Metallic and sometimes earthy
Cleavage Perfect in one direction
Diaphaneity Opaque
Mohs hardness One to two
Crystal System Hexagonal
Tenacity Flexible
Density 2.09 – 2.23 g/cm3 (Measured) 2.26 g/cm3 (Calculated)
Fracture Micaceous

Graphite Optical properties

Anisotropism Extreme
Color / Pleochroism Strong
Signs of Optic Visibility Uniaxial ()
Birefringence extreme birefringence

The appearance and use of graphite
The reduction of carbon compounds causes the degradation of deposits containing carbon. The main component found in igneous stones. This occurs due to the reduction sedimentary carbon compound in metamorphic rock. Also, it can be found in meteorites and magmatic rocks. Quartz, calcite and mica are minerals that have a close relationship to this mineral. The main mineral exporters are China, Mexico Canada Brazil Madagascar.

Synthetic graphite
Synthetic graphite can be made from graphitized carbon obtained from hydrocarbons using CVD, at a higher temperature than 2500 K. It is also possible to obtain it from supersaturated carbides by decomposing them or by crystallizing the metal in molten state.

Synthetic graphite and “artificial graphite”, both terms are often used interchangeably. Synthetic graphite is more preferred due to the fact that their crystals are believed to be composed of macromolecular carbon. The term CVD is also used to describe carbide residues, pyrolytic and synthetic graphite. The definition is the same for this common usage. Acheson and electrophotography are two of the most important synonyms for synthesized graphite.

The Applied Area
Natural graphite has many uses, such as refractory, expanded graphite (brake pads), casting surfaces, brake pad, and lubrication.
The graphite used in crucibles was very large, but the graphite required for carbon-magnesia bricks was not as large. These and other products now have greater flexibility in the size of flake graphite required.
Graphite use in batteries has grown over the last 30 Years. In the major battery technologies, both natural and synthetic materials may be used for electrodes.
The lithium-ion battery used in the new car, for instance, contains almost 40 kilograms of graphite.
The main use of natural graphite for steelmaking is to increase carbon content in the molten steel. It can be used also to lubricate extrusion moulds.
The use of natural amorphous flake and fine flakes graphite for brake linings and brake shoes in heavy (non automotive) vehicles is increasing as asbestos needs to be replaced.
Foundries clean molds with amorphous, thin flake like coatings. If you paint it inside the mold then let it air dry, it will leave behind a fine graphite layer that helps to separate the castings after the molten steel has cooled.

Synthetic graphite has many uses
High focus pyrolytic (HOPG), the best synthetic graphite, is of the highest quality. In scientific research it is used to calibrate scanners and scanning probe microscopes.
The electrodes melt scrap steel and iron in electric arc kilns (most steel furnaces) and, sometimes, direct reduced iron. The mixture of coal tar and petroleum coke is used to make them.
Graphite Carbon electrodes are also employed in the electrolytic aluminium smelting. Synthetic electrodes are used at a small scale in the discharge (EDM) process for making plastic injection moulds.
Special grades, such as the gilsocarbon graphite, can be utilized as a neutron moderator and matrix in nuclear reactors. In the recommended fusion-reactor, it is recommended that low neutrons cross sections be used.
The carbon nanotubes can also be found in heat-resistant composites, such as the reinforced carbon-carbon material (RCC). Commercial structures made from carbon fiber graphite materials include golf shafts, bicycle frame, sports car body panels and the body panel of the Boeing 787 Dreamliner.
To prevent static build-up, modern smokeless powders have a graphite coating.
At least three different radar-absorbing materials contain it. Sumpf, Schornsteinfeger and rubber are mixed to form U-shaped Snorkels. This reduces the radar cross section. The F-117 Nighthawk floor tiles were also used for secretly hitting fighter jets.
Graphite Composites are used in the LHC beam collection as high-energy particle absorbers.
Graphite Recycling
The most common way to recover graphite occurs when synthetic graphite electrodes are made and then cut up into small pieces, or are discarded by turning them on a lathe. Or when the electrodes have been used all the way down to the electrode holders. Replace the old with new electrodes. However, most of the older electrodes are still present. After crushing and sizing the graphite, it is used mainly to increase the carbon in molten steel. Some refractories contain refractory material, but these are not usually caused by graphite. For example, the bulk materials containing graphite (such as bricks of carbon magnesia containing only 15 to 25 percent graphite), usually have very little graphite. Carbon magnesite can be recovered.

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