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What is zirconium-nitride (ZnN)?
The zirconium-nitride, with its chemical formula ZrN, has excellent corrosion resistance. It also has a high degree of hardness, lubricity, and ductility. This coating is attractive due to its many properties. It is applied using physical vapor deposit. It is available in a yellow crystalline coating or attractive golden coating.
The zirconium-nitride has a physical and chemical property of 7.09 and a microhardness between 9800 and 19600 MPa. It also has a melting point of 2980 degrees Celsius plus or minus fifty. Zirconium is soluble only in hydrofluoric and concentrated sulfuric acids. Zirconium (ZrN), because of its properties, can be used in various ways.
ZrN grown through physical vapor deposit (PVD), is similar in color to elemental Gold. ZrN has a resistivity of 12.0mO*cm at room temperature, a temperature coefficient resistivity of 5.6*10-8O*cm/K and a superconducting threshold temperature of 10.4K. The relaxation lattice parameters is 0.4575nm. The elastic modulus and hardness are 450 GPa.
What is zirconium-nitride used for?
Zirconium Nitride is a ceramic hard material, similar to titanium nitride. It also acts as a cement like refractory. This material can be used to make refractory materials as well as laboratory crucibles, cermets or cermet alloys. Physical vapor deposition is a coating method that is commonly used on medical equipment, industrial components (especially drill bits), aerospace and automotive parts, as well as other parts exposed to harsh environments and high wear. In the case of alloying ZrN with Al, electronic structure is developed from the cubic ZrN’s local octahedral symmetry. As the Al concentration increases, this symmetry is distorted and becomes more complex, with a higher degree of hardness.
For rockets, zirconium-nitride is recommended as a fuel tank lining.
Zirconium Nitride (ZrN) compounds are composed of different crystal structures. These vary depending on their composition. ZrN is an alloy compound that has been discovered in the ZrN system. Not only do they have excellent chemical characteristics, but they can also be used in junctions, diffusion laminations, low temperature instruments, etc. These compounds can be used in three-dimensional integrated electronic coils as well as metal-based semiconductor transistors. The ZrN compounds have superior wear resistance to pure zirconium, as well as oxidation, corrosion and wear resistance. In addition, they have a greater superconducting threshold temperature.
Preparation and use of zirconium powder
The main processes for the synthesis of zirconium oxide powder include direct nitridation using nitrogen on Zr metals, high-energy ball milling, microwave plasma, benzene method, aluminum reduction, magnesium thermal, carbothermal nitridation. There are suitable routes for various particle morphologies and sizes. The mass production of Zirconium Nitride and other Transition Metal Nitrides is possible. It should be noted, that due to the formation solid solution within the ZrN – ZrC – “ZrO” System, the final nitriding product in CRN, or CN, is typically represented by this formula Zr (N – C – O). It is necessary to perform a CRN two-step process. The nitrite is converted from zirconium carburide (ZrC), which was produced earlier as an intermediate. The CN method is a direct nitridation in the presence carbon of ZrO2, and it only requires a single heat treatment. It is possible that the latter method can be more time- and energy-efficient in producing zirconium-nitride.
In oxygen reduction, zirconium nitride surpasses platinum
Pt-based materials play an important role in microelectronics, anti-cancer medicines, automotive catalysts, and electrochemical energy-conversion equipment. Pt, the most common catalyst for oxygen reduction reactions (ORR), is used in fuel cell and metal-air battery applications. Its toxicity, scarcity, and cost limit its potential use. In this study, we demonstrate that nano-particles of zirconium (ZrN), can replace or exceed Pt in ORR catalysts for alkaline environments. The synthesized ZrN (nanoparticles) exhibit high oxygen-reduction performance, and are as active as the commonly used commercial catalyst Pt/C. After 1000 ORR cycle, both materials had the same half wave potential (E1/2 = 0.80 V), but ZrN was more stable (DE1/2 than = 3 mV). In 0.1 M KOH. ZrN is also more efficient and has higher cycles in zinc-air battery than Pt/C. ZrN replacing Pt may lower costs and encourage the use electrochemical energy devices. ZrN could also be useful in catalytic systems.
Enhanced Photoluminescence Combined with a Periodic array of Organic Dyes and Zirconium Nitride Nanoparticles
Due to their excellent optical properties, noble metals like gold have been used in plasma technology. The melting temperature of gold, particularly in nanoscale applications, is low. These limitations in material are a barrier to the exploration of plasmons for multiple applications. Transition metal nitrides are promising substitutes for conventional materials because of their high mechanical and thermo-mechanical stability, and also acceptable plasma properties in the visible range. Zirconium (ZrN), a promising material substitute, has a carrier density higher than titanium (TiN), the gold Supplementary material most studied. In this research, we made a periodic ZrN-nanoparticle array and found out that the ZrN array increased the photoluminescence in the organic dyes. This photoluminescence was 9.7 times stronger when viewed under visible light. The experiments confirmed that ZrN is a good alternative to gold for further developing plasmons, and relieving the limitations associated to conventional materials.
(aka. Technology Co. Ltd., a trusted global chemical supplier & manufacturer has been providing high-quality Nanomaterials and chemicals for over 12 Years. Currently, we have developed a number of materials. Our company produces zirconium-nitride with high purity and fine particle size. Send us an e-mail or click the desired products to Send an inquiry .
The zirconium-nitride has a physical and chemical property of 7.09 and a microhardness between 9800 and 19600 MPa. It also has a melting point of 2980 degrees Celsius plus or minus fifty. Zirconium is soluble only in hydrofluoric and concentrated sulfuric acids. Zirconium (ZrN), because of its properties, can be used in various ways.
ZrN grown through physical vapor deposit (PVD), is similar in color to elemental Gold. ZrN has a resistivity of 12.0mO*cm at room temperature, a temperature coefficient resistivity of 5.6*10-8O*cm/K and a superconducting threshold temperature of 10.4K. The relaxation lattice parameters is 0.4575nm. The elastic modulus and hardness are 450 GPa.
Zirconium Nitride is a ceramic hard material, similar to titanium nitride. It also acts as a cement like refractory. This material can be used to make refractory materials as well as laboratory crucibles, cermets or cermet alloys. Physical vapor deposition is a coating method that is commonly used on medical equipment, industrial components (especially drill bits), aerospace and automotive parts, as well as other parts exposed to harsh environments and high wear. In the case of alloying ZrN with Al, electronic structure is developed from the cubic ZrN’s local octahedral symmetry. As the Al concentration increases, this symmetry is distorted and becomes more complex, with a higher degree of hardness.
For rockets, zirconium-nitride is recommended as a fuel tank lining.
Zirconium Nitride (ZrN) compounds are composed of different crystal structures. These vary depending on their composition. ZrN is an alloy compound that has been discovered in the ZrN system. Not only do they have excellent chemical characteristics, but they can also be used in junctions, diffusion laminations, low temperature instruments, etc. These compounds can be used in three-dimensional integrated electronic coils as well as metal-based semiconductor transistors. The ZrN compounds have superior wear resistance to pure zirconium, as well as oxidation, corrosion and wear resistance. In addition, they have a greater superconducting threshold temperature.
Preparation and use of zirconium powder
The main processes for the synthesis of zirconium oxide powder include direct nitridation using nitrogen on Zr metals, high-energy ball milling, microwave plasma, benzene method, aluminum reduction, magnesium thermal, carbothermal nitridation. There are suitable routes for various particle morphologies and sizes. The mass production of Zirconium Nitride and other Transition Metal Nitrides is possible. It should be noted, that due to the formation solid solution within the ZrN – ZrC – “ZrO” System, the final nitriding product in CRN, or CN, is typically represented by this formula Zr (N – C – O). It is necessary to perform a CRN two-step process. The nitrite is converted from zirconium carburide (ZrC), which was produced earlier as an intermediate. The CN method is a direct nitridation in the presence carbon of ZrO2, and it only requires a single heat treatment. It is possible that the latter method can be more time- and energy-efficient in producing zirconium-nitride.
In oxygen reduction, zirconium nitride surpasses platinum
Pt-based materials play an important role in microelectronics, anti-cancer medicines, automotive catalysts, and electrochemical energy-conversion equipment. Pt, the most common catalyst for oxygen reduction reactions (ORR), is used in fuel cell and metal-air battery applications. Its toxicity, scarcity, and cost limit its potential use. In this study, we demonstrate that nano-particles of zirconium (ZrN), can replace or exceed Pt in ORR catalysts for alkaline environments. The synthesized ZrN (nanoparticles) exhibit high oxygen-reduction performance, and are as active as the commonly used commercial catalyst Pt/C. After 1000 ORR cycle, both materials had the same half wave potential (E1/2 = 0.80 V), but ZrN was more stable (DE1/2 than = 3 mV). In 0.1 M KOH. ZrN is also more efficient and has higher cycles in zinc-air battery than Pt/C. ZrN replacing Pt may lower costs and encourage the use electrochemical energy devices. ZrN could also be useful in catalytic systems.
Due to their excellent optical properties, noble metals like gold have been used in plasma technology. The melting temperature of gold, particularly in nanoscale applications, is low. These limitations in material are a barrier to the exploration of plasmons for multiple applications. Transition metal nitrides are promising substitutes for conventional materials because of their high mechanical and thermo-mechanical stability, and also acceptable plasma properties in the visible range. Zirconium (ZrN), a promising material substitute, has a carrier density higher than titanium (TiN), the gold Supplementary material most studied. In this research, we made a periodic ZrN-nanoparticle array and found out that the ZrN array increased the photoluminescence in the organic dyes. This photoluminescence was 9.7 times stronger when viewed under visible light. The experiments confirmed that ZrN is a good alternative to gold for further developing plasmons, and relieving the limitations associated to conventional materials.
(aka. Technology Co. Ltd., a trusted global chemical supplier & manufacturer has been providing high-quality Nanomaterials and chemicals for over 12 Years. Currently, we have developed a number of materials. Our company produces zirconium-nitride with high purity and fine particle size. Send us an e-mail or click the desired products to Send an inquiry .